An easily accessible Re-based catalyst for the selective conversion of methanol: evidence for an unprecedented active site structure through combined operando techniques.

نویسندگان

  • Anthony Yoboué
  • Audrey Susset
  • Asma Tougerti
  • Daniel Gallego
  • Sudarsan Venkat Ramani
  • Malathi Kalyanikar
  • Dmitriy S Dolzhnikov
  • Sileshi G Wubshet
  • Yilun Wang
  • Sylvain Cristol
  • Valérie Briois
  • Camille La Fontaine
  • Régis M Gauvin
  • Jean-François Paul
  • Elise Berrier
چکیده

Heterogeneous Re/SiO(2) catalysts prepared using a one pot sol-gel synthesis were found to display high activity in the direct, selective methanol conversion to methylal, which is correlated to an unprecedented rhenium oxide structure.

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عنوان ژورنال:
  • Chemical communications

دوره 47 14  شماره 

صفحات  -

تاریخ انتشار 2011